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Which dye classes can thiourea dioxide be used with?

Direct answer

Thiourea dioxide is a general-purpose reducing agent that covers most processes needing reduction, but how it is applied varies a great deal by dye class: in some it is the main agent, in others it suits stripping only, and in others it must be blended.

Suitability matrix

Dye classProcessSuitabilityNote
Vat dyesVat dyeingUsable in exhaust dyeingPad-steam replacement needs a corrected dye formulation and may shift the hue
Sulphur dyesDyeing and strippingSuitableCommon on cotton and cotton blends
IndigoReductionSuitable80 °C, 1.5 to 3.5 g/L
Reactive dyesStripping and reworkSuitableGood on light and medium shades; deep shades need a blend
Disperse dyes (polyester)Reduction clearing after dyeingBest application0.5 to 1.0 g/L, 70 to 95 °C
Disperse dyes (polyester)StrippingSuitableWatch for over-reduction shifting the shade
Acid and direct dyes (wool, silk)StrippingSuitableMild alkali, 60 to 80 °C; control strength loss
Pigment coloration-Not applicableA reducing agent does not act on pigment particles

Three general rules

1. Alkali is essential: without adequate pH there is no reduction; add alkali before the product

2. Temperature must be sufficient: full effect above 70 °C; 70 to 95 °C for reduction clearing, boiling for stripping and machine cleaning

3. Blend for deep shades: black and grey stripping at roughly 1:10 (thiourea dioxide : hydrosulfite)

Two cases that need a bench trial

  • Vat dyeing by pad-steam: hue errors are possible and the formulation has to be corrected
  • Reduction-sensitive dyes (certain anthraquinone disperse dyes and some reactive blues): measure colour difference as delta E

Sources

The above reflects established industry practice and the ranges in our technical data sheet; confirm by bench trial for the specific dye.